Melt Electrospinning of PET and Composite PET-Aerogel Fibers: An Experimental and Modeling Study

Increasingly advanced applications of polymer fibers are driving the demand for new, high-performance fiber types. One way to produce polymer fibers is by electrospinning from polymer solutions and melts. Polymer melt electrospinning produces fibers with small diameters through solvent-free processing and has applications within different fields, ranging from textile and construction, to the biotech and pharmaceutical industries. Modeling of the electrospinning process has been mainly limited to simulations of geometry-dependent electric field distributions. The associated large change in viscosity upon fiber formation and elongation is a key issue governing the electrospinning process, apart from other environmental factors. This paper investigates the melt electrospinning of aerogel-containing fibers and proposes a logistic viscosity model approach with parametric ramping in a finite element method (FEM) simulation. The formation of melt electrospun fibers is studied with regard to the spinning temperature and the distance to the collector. The formation of PET-Aerogel composite fibers by pneumatic transport is demonstrated, and the critical parameter is found to be the temperature of the gas phase. The experimental results form the basis for the electrospinning model, which is shown to reproduce the trend for the fiber diameter, both for polymer as well as polymer-aerogel composites

Thermal Properties of Novel Phase-Change Materials Based on Tamanu and Coconut Oil Encapsulated in Electrospun Fiber Matrices

The accumulation of thermal energy in construction elements during daytime, and its release during a colder night period is an efficient and green way to maintain a comfortable temperature range in buildings and vehicles. One approach to achieving this goal is to store thermal energy as latent heat of the phase transition using the so-called phase-change materials (PCMs). Vegetable oils came recently into focus as cheap, widely available, and environmentally friendly PCMs. In this study, we report the thermal properties of PCMs based on tamanu and coconut oils in three configurations: pure, emulsion, and encapsulated forms. We demonstrate the encapsulation of pure coconut- and tamanu-oil emulsions, and their mixtures and mixtures with commercial PCM paraffins in fiber matrices produced by a coaxial electrospinning technique. Polycaprolactone (PCL) was used as a shell, the PCM emulsion was formed by the studied oils, and sodium dodecyl sulfate (SDS) and polyvinyl alcohol (PVA) were used as emulsifiers. The addition of commercially available paraffin RT18 into a 70/30 mixture of coconut and tamanu oil, successfully encapsulated in the core of a PCL shell, demonstrated latent heats of melting and solidification of 63.8 and 57.6 kJ/kg, respectively

Thermal Analysis of Organic and Nanoencapsulated Electrospun Phase Change Materials

Latent heat stored in phase change materials (PCM) can greatly improve energy efficiency in indoor heating/cooling applications. This study presents the materials and methods for the formation and characterization of a PCM layer for a latent heat thermal energy storage (LHTES) application. Four commercially available PCMs comprising the classes of organic paraffins and organic non-paraffins were selected for thermal storage application. Pure organic PCM and PCM in water emulsions were experimentally investigated. PCM electrospun microfibers were produced by a co-axial electrospinning technique, where solutions of Polycaprolactone (PCL) 9% w/v and 12% w/v in dichloromethane (DCM) were used as the fiber shell materials. PCM emulsified with sodium dodecyl sulfate (SDS), and Polyvinylalcohol 10% w/v (PVA) constituted the core of the fibers. The thermal behavior of the PCM, PCM emulsions, and PCM electrospun fibers were analyzed with differential scanning calorimetry (DSC). A commercial organic paraffin with a phase change temperature of 18 °C (RT 18) in its pure and emulsified forms was found to be a suitable PCM candidate for LHTES. The PVA-PCM electrospun fiber matrix of the organic paraffin RT18 with a PCL concentration of 12% w/v showed the most promising results leading to an encapsulation efficiency of 67%